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| physics_chemistry:orbitals:y [2026/06/20 15:44] – Maurits W. Haverkort | physics_chemistry:orbitals:y [2026/06/20 15:45] (current) – Maurits W. Haverkort | ||
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| - | The complex spherical harmonics are defined as the simulatneous | + | The complex spherical harmonics are defined as the simultaneous |
| $$ | $$ | ||
| - | Y_l^{(m)} = \frac{\sqrt{2 l+1}}{2 \sqrt{\pi }} \sqrt{\frac{(l-m)!}{(l+m)!}} e^{i m \phi } P_l^{(m)}(\cos (\theta )), | + | Y_l^{(m)}(\theta, |
| $$ | $$ | ||
| with $l$ the angular momentum and $m$ the z projection of the angular momentum, $-l \leq m\leq l$. $P_l^{(m)}$ are the associated Legendre polynomials. For positive $m$ these are defined in terms of the unassociated Legendre polynomials as: | with $l$ the angular momentum and $m$ the z projection of the angular momentum, $-l \leq m\leq l$. $P_l^{(m)}$ are the associated Legendre polynomials. For positive $m$ these are defined in terms of the unassociated Legendre polynomials as: | ||