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physics_chemistry:orbitals:y [2016/10/10 09:40] – external edit 127.0.0.1physics_chemistry:orbitals:y [2026/06/20 15:45] (current) Maurits W. Haverkort
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 ====== Spherical Harmonic (Y) ====== ====== Spherical Harmonic (Y) ======
 ~~NOTOC~~ ~~NOTOC~~
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 ### ###
-The spherical harmonics are defined as+The complex spherical harmonics are defined as the simultaneous eigenstates of $L^2$ and $L_z$ and given by
 $$ $$
-Y_l^{(m)} = \frac{\sqrt{2 l+1}}{2 \sqrt{\pi }} \sqrt{\frac{(l-m)!}{(l+m)!}} e^{i m \phi } P_l^{(m)}(\cos (\theta )),+Y_l^{(m)}(\theta,\phi) = \frac{\sqrt{2 l+1}}{2 \sqrt{\pi }} \sqrt{\frac{(l-m)!}{(l+m)!}} e^{i m \phi } P_l^{(m)}(\cos (\theta )),
 $$ $$
 with $l$ the angular momentum and $m$ the z projection of the angular momentum, $-l \leq m\leq l$. $P_l^{(m)}$ are the associated Legendre polynomials. For positive $m$ these are defined in terms of the unassociated Legendre polynomials as: with $l$ the angular momentum and $m$ the z projection of the angular momentum, $-l \leq m\leq l$. $P_l^{(m)}$ are the associated Legendre polynomials. For positive $m$ these are defined in terms of the unassociated Legendre polynomials as:
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 ====== Different orbital basis sets used ====== ====== Different orbital basis sets used ======
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