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documentation:tutorials:nio_ligand_field:nixs_m45 [2016/10/10 09:41]
127.0.0.1 external edit
documentation:tutorials:nio_ligand_field:nixs_m45 [2018/03/20 11:06] (current)
Maurits W. Haverkort
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 Inelastic x-ray scattering IXS (non-resonant) nIXS or x-ray Raman scattering allows one to measure non-dipolar allowed transitions. A powerful technique to look at even $d$-$d$ transitions with well defined selection rules \cite{Haverkort:​2007bv,​ vanVeenendaal:​2008kv,​ Hiraoka:​2011cq},​ but can also be used to determine orbital occupations of rare-earth ions that are fundamentally not possible to determine using dipolar spectroscopy \cite{Willers:​2012bz}. Inelastic x-ray scattering IXS (non-resonant) nIXS or x-ray Raman scattering allows one to measure non-dipolar allowed transitions. A powerful technique to look at even $d$-$d$ transitions with well defined selection rules \cite{Haverkort:​2007bv,​ vanVeenendaal:​2008kv,​ Hiraoka:​2011cq},​ but can also be used to determine orbital occupations of rare-earth ions that are fundamentally not possible to determine using dipolar spectroscopy \cite{Willers:​2012bz}.
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 +This tutorial compares calculated spectra to experiment. In order to make the plots you need to download the experimental data. You can download them in a zip file here {{ :​documentation:​tutorials:​nio_crystal_field:​nio_data.zip |}}. Please unpack this file and make sure to have the folders NiO_Experiment and NiO_Radial in the same folder as you do the calculations. And as always, if used in a publication,​ please cite the original papers that published the data. 
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